巴西专利BR112019011506A2 higher bio-based biodegradable toiletries

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专利摘要:
The present invention relates to sanitary articles such as disposable diapers, adult incontinence pads, feminine hygiene products, and higher bio-based biodegradable polymer absorbent pads. Hygienic articles include a top sheet, an absorbent core and a back sheet. The topsheet is comprised of biodegradable polyester polyol polymer foam that can be configured to absorb liquid from the user's body and can be impregnated with superabsorbent polymer. The absorbent core may be comprised of a superabsorbent polymer including a cross-linked and / or partially neutralized polyacrylic acid polymer, cross-linked polyacrylic acids or cross-linked starch acrylic acid graft polymers. the backsheet may be comprised of polylactone polymers having generally hydrophobic characteristics. In preferred embodiments, polymeric materials comprising the topsheet, the absorbent core and the backsheet are formed from high biobased raw materials.
公开号:BR112019011506A2
申请号:R112019011506-4
申请日:2017-12-06
公开日:2019-11-05
发明作者:H Sookraj Sadesh
申请人:Novomer Inc；
IPC主号:

专利说明:

BIODEGRADABLE HYGIENIC ARTICLES WITH HIGHER BIOLOGICAL BASIS
FIELD OF THE INVENTION [0001] The present invention relates to new hygienic articles, such as disposable diapers, intimate pads for adult incontinence, intimate pads and the like, comprised of biodegradable polymers that have a higher bio-based content. Specifically, the present invention provides hygienic articles including a liquid-permeable topsheet, a liquid-impermeable backsheet, an absorbent core, elastic elements and adhesive fasteners made of polymers with the highest biodegradability and bio-based content. Advantageously, the present invention provides more environmentally responsible hygienic applications.
BACKGROUND OF THE INVENTION [0002] In general, a polymer is a larger molecule consisting of multiple smaller repeated molecules known as monomers. During a process known as polymerization, the monomers can be covalently linked to each other to form larger polymer chains. The composition and arrangement of the monomers can determine the characteristics of the polymer, for example,
determining biodegradability and The content from the base biological polymer. [0003] 0 biological base content of polymer refers to to the sources of raw materials to leave of which
monomers are derived. Specifically, the degree of content of the biological base depends on the amount of carbon in the
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2/23 monomers that are derived from biological, recycled, renewable or otherwise sustainable materials. Such biological materials can include sources such as crop residues, wood residues, grasses, municipal solid residues and algae. A polymer with a higher bio-based content may be preferable for use in sustainable and environmentally responsible applications.
[0004] Biodegradable polymers can also be beneficial in environmentally responsible applications. Biodegradable polymers generally include a backbone composed of linked organic molecules that can decompose by natural processes into smaller, environmentally compatible molecules. The specific chemical composition of the monomers in biodegradable polymers will determine which smaller molecules will be produced by decomposition, the mechanisms by which decomposition occurs and the rate at which decomposition occurs.
[0005] Many conventional polymers may not consist of monomers that confer characteristics of biodegradability or some degree of biobased content. In addition, modifying conventional processes to produce environmentally responsible polymers can be expensive, require long production cycles and / or be difficult to modify.
[0006] In general, hygienic articles such as disposable diapers, adult incontinence pads, feminine hygiene products and sanitary pads include an absorbent core for receiving and retaining liquids. For absorbent articles to work efficiently, the absorbent core must receive
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3/23 quickly liquid in its structure, preferably separating the liquids from the user's body with a special top sheet layer. Liquids can easily penetrate the topsheet and be absorbed by the absorbent core. Retained fluids may also not penetrate a hydrophobic backsheet that is positioned further away from the user's body.
[0007] The top sheet is generally moldable, smooth and non-irritating to the user's skin, while maintaining a liquid-permeable feature, allowing liquids to quickly penetrate through its thickness. A conventional topsheet can be manufactured from a wide range of materials, such as porous foams, reticulated foams, plastic films with openings, natural fibers (for example, wood or cotton fibers), synthetic fibers (for example, polyester fibers or polypropylene) or a combination of natural and / or synthetic fibers. Conventionally, the top sheet is made of a material designed to insulate the user's skin from liquids contained in the absorbent core.
[0008] The backsheet is generally impermeable to liquids and is conventionally manufactured from a thin plastic film, such as polypropylene or polyethylene, although other materials can also be used. The back sheet prevents the fluids that are absorbed and contained in the absorbent core from soiling the items of clothing that come in contact with the hygienic item, such as sheets and underwear. Similar to the top sheet, the back sheet is generally flexible and moldable to readily adapt to the overall shape and contours of the
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4/23 user's body.
[0009] The absorbent core is generally positioned between the topsheet and the backsheet to form the hygienic article. The absorbent core is generally compressible, adaptable, non-irritating to the user's skin and capable of absorbing and retaining liquids and certain bodily excretions. The absorbent core can conventionally comprise laminates or combinations of various
layers or wefts like necessary of materials. [0010] Exist an need to improve biodegradability From hygienic articles. This invention solve it is need providing articles hygienic compounds of material polymeric with
increased biodegradability and biological base content.
SUMMARY OF THE INVENTION [0011] The present invention relates to hygienic articles that provide multiple benefits over those currently available, minimizing the impact of such articles on the environment while, at the same time, improving the comfort of such articles for the user. Thus, a benefit is a hygienic article composed of biodegradable polymers with a high content of biological base that minimizes the damage of these articles to the environment. In addition, the incorporation of highly adsorbent materials in the top sheet, in accordance with this invention, reduces the feeling of moisture against the skin of those using hygienic articles.
[0012] In one embodiment, the invention constitutes a hygienic article having a top sheet, a back sheet and an absorbent core. The top sheet consists of a
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5/23 heterogeneous physical mixture of biodegradable polyester polyol polymer and, relative to the mass of the polyester polymer, a smaller mass of a superabsorbent polymer dispersed through the topsheet as separate particles. The absorbent core comprises a biodegradable superabsorbent polymer having an inner side positioned adjacent and fixed with respect to said topsheet. The backsheet comprises a liquid impermeable and biodegradable polymer positioned adjacent to an external side of said absorbent core and fixed in relation to said adsorbent core.
[0013] In another aspect of the invention, the topsheet may comprise a biodegradable polyester polyol polymer, with a mesh (lattice) that retains the superabsorbent particles.
[0014] In another aspect, the network may comprise pores that are impregnated with the superabsorbent polymer to provide the heterogeneous dispersion of the biodegradable superabsorbent polymer.
[0015] The top sheet will have an absorbent face positioned in the vicinity of the absorbent core and a corporeal face facing outward from the hygienic article and the concentration of superabsorbent polymer may be higher close to the corporeal face in relation to the concentration close to the absorbent face or concentration of superabsorbent polymer can be higher in the vicinity of the absorbent face in relation to the concentration in the vicinity of the body face.
[0016] In some aspects of the invention, one or more derivatives of polyester polyols, polylactones and / or polyacrylic acid can be used to form elements
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6/23 biodegradable elastics. In some embodiments, one or more polyester polyols, polylactones and / or polyacrylic acid derivatives can be used to form biodegradable adhesive fixatives.
[0017] In other respects, the topsheet may comprise a biodegradable polyester polyol polymer in the form of a foam with superabsorbent particles interspersed as a physical mixture. The foam may consist of a network in which the superabsorbent particles are dispersed. In other embodiments, the foam can define pores that are impregnated with a heterogeneous dispersion of biodegradable superabsorbent polymer.
[0018] Polyester polyol polymers suitable for the topsheet include multiple functional groups of carbonyl, carbonate, acetal, ether, nitrile, urethane, urea, imide, anhydride, phosphate and / or cyanocrylate in the main chain to facilitate biodegradability. The polyol can include cross-links between the polymer's main chains, allowing the formation of pores in a three-dimensional structure. The composition of the polyol and the crosslinking molecules can determine the pore size and the general structural properties of the polyol network. The pore size and the general structural properties of the polyol network can determine the capacity of the superabsorbent polymer and the inter-network dispersion distance for the superabsorbent polymer.
[0019] In other aspects of the invention, biodegradable superabsorbent foam is produced in at least two stages, including polyol polymerization and formation
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7/23 of foam from the mesh while impregnating the superabsorbent polymer into the pores of the mesh.
[0020] In preferred embodiments, the backsheet of the present invention includes polylactone, polybutylene succinate and / or polybutylene succinate derivatives. In certain preferred embodiments, the backsheet may consist of polylactone polymers comprising β-lactone monomers and having linear chains of repeated monomer units containing carbon and oxygen atoms provided by a feed of β-lactone produced from the carbonylation of a epoxide containing carbon atoms from a renewable source. In some embodiments, polylactone polymers include crosslinking agents such as vinyl groups, for example, N, N'-methylene-bisacrylamide, N, N'ethylene-bis-methacrylamide, hexamethylene-bis-acrylamide, trialyl amine, dimethacrylate ethylene glycol, trimethylolpropane trimethacrylate, pentaerythritol trimethacrylate and allyl methacrylate. In certain preferred embodiments, polylactones can have or be modified to have a higher degree of hydrophobicity.
[0021] In certain preferred embodiments of the present invention, the absorbent core may have an inner side positioned close to a topsheet and an outer side positioned close to a backsheet and may consist of polyacrylic acid derivatives. In preferred aspects of the invention, materials for the absorbent core are produced by new methods and processes that impart a high
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8/23 biological base in the absorbent core. The methods and processes for producing acrylic acid from β-propiolactone involve the polymerization of β-propiolactone with an ionic initiator in a reactor to produce a polymer intermediate with a polyacrylic acid structure and a plurality of polypropiolactone side chains. Advantageously, the biodegradable polyacrylic acid derivatives formed may have a higher content of the biological base.
[0022] In some respects, polymers produced according to any of the methods described in this document are provided.
[0023] In some variations of the foregoing, polymers
have content biological i overcame now 0% and infer now 100%. In certain variations of the precedent, < polymers have a biological hair content any less 10%, fur any less 20%, fur least 30%, at least minus 40%, fur any less 50%, fur any less 60%, at least 70%, at least 80%, fur any less 90%, fur any less 95% at least 96% by any less 97%, fur any less 98%, fur
at least 99%, at least 99.5%, at least 99.9%, at least 99.99%, or 100%.
[0024] In some variations, the biological content (also called the biological base content) can be determined based on the following:% biological content or biological base content = [Bio (Organic) Carbon] / [Carbon (Organic) ) Total]] * 100%, as determined by ASTM D6866 (Standard Test Methods for Determining the Bio-based Content of Solid, Liquid and Gaseous Samples Using Radiocarbon Analysis).
[0025] The biological content of polymers may depend
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9/23 based on the biological content of the β-lactone used. For example, in some variations of the methods described in this document, the β-lactone used to produce the polymers described in this document may have a biological content greater than 0% and less than 100%. In certain variations of the modes described in this document, the βlactone used to produce the polymers described in this document can have a biological content of at least 10%, at least 20%, at least 30%, at least 40%, at least 50 %, at least 60%, at least 70%, at least 80%, at least 90%, at least 95%, at least 96%, at least 97%, at least 98%, at least 99%, at least 99 , 5%, at least 99.9%, at least 99.99% or 100%. In certain variations, β-lactone derived from renewable sources is used. In other variations, at least a portion of the β-lactone used is derived from renewable sources, and at least a portion of the β-lactone is derived from non-renewable sources.
[0026] The content of the biological base of β-propiolactone may depend, for example, on the biological content of ethylene oxide and the carbon monoxide used. In some variations, both ethylene oxide and carbon monoxide are derived from renewable sources.
[0027] In some variations of the foregoing, the polymer
has biodegradability at least 10%, fur any less 20%, fur minus 30%, fur least 40%, at least any less 50% , fur minus 60%, at least 70%, at least 80%, fur less s 90%, fur any less 95% by any less 96% at least 97%, fur any less 98%, fur minus 99%, fur at least 99.5%, at least 99.9%, fur any less 99.99%, or 100%.
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10/23 [0028] In some variations of the above, biodegradable is as defined and determined based on ASTM D5338-15 (Standard Test Method for Determining Aerobic Biodegradation of Plastic Materials Under Controlled Composting Conditions, Incorporating Themophilic Temperatures).
[0029] An objective of the present invention is to provide hygienic, absorbent articles with improved properties in the handling of fluid waste, while maintaining characteristics of biodegradability and content of the biological base.
[0030] Several other features and advantages of the present invention will emerge from the description that follows.
[0031] Although this description is susceptible to several modifications and alternative forms, specific exemplary modalities have been shown by way of example and described in detail in this document. It should be understood, however, that there is no intention to limit the disclosure to the particular modalities disclosed, however, on the contrary, the intention is to cover all modifications, equivalents and alternatives that are within the scope of the disclosure, as defined in the attached claims. .
DETAILED DESCRIPTION OF THE MODALITIES [0032] The following description includes preferred embodiments of the present invention that are directed to biodegradable polyol polymers having a higher biobased carbon content. It should be recognized, however, that this description is not intended to be a limitation
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11/23 to the scope of the present disclosure, but rather a description of exemplary aspects.
[0033] Definitions of specific functional groups and chemical terms are described in more detail below. Chemical elements are identified according to the Periodic Table of Elements, CAS version, Handbook of Chemistry and Physics, 15th Ed., Inner cover, and specific functional groups are generally defined as described in this document. In addition, general principles of organic chemistry, as well as specific functional moieties and reactivity, are described in Organic Chemistry, Thomas Sorrell, Science Books University, Sausalito, 1999; Smith and March March's Advanced Organic Chemistry, 5th Edition, John Wiley & Sons, Inc., New York, 2001; Larock, Comprehensive Organic Transformations, VCH Publishers, Inc., New York, 1989; Carruthers, Some Modern Methods of Organic Synthesis, 3rd Edition, Cambridge University Press, Cambridge, 1987; the entire content of each of them being incorporated into this document as a reference.
[0034] The term polymer, as used in this document, refers to a molecule of high relative molecular mass, whose structure comprises multiple repetitions of units derived, real or conceptually, from molecules of low relative molecular mass. In some respects, a polymer is made up of just one species of monomer (for example, polyEO). In some respects, a polymer is a copolymer, terpolymer, heteropolymer, block copolymer or conical heteropolymer of one or more epoxides.
[0035] As used in this document, the term
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12/23 catalyst refers to a substance whose presence increases the rate of a chemical reaction, while it is not being consumed or undergoing a permanent chemical change itself.
[0036] Biodegradability and biodegradability refer to the ability of a material to be broken (decomposed) quickly by the action of living organisms, such as bacteria, fungi, microorganisms or other biological means, in which quickly and typically less than 10 years, 5 years, for 2 years.
[0037] Sustainable material and sustainable polymer mean a biodegradable material and polymer, respectively, which is derived, at least in part, from green sources and has a percentage of green substituents
equal to one minimum 10% and more typically 20%, 50%, 75%, 90%, 95% or 10 0% of total amount in carbon and hydrogen in the material. [0038] As an employee in this document , the term about preceding one or more values numeric
means the numerical value ± 5%. It should be understood that the reference to a value or parameter in this document includes (and describes) aspects that are directed to that value or parameter itself. For example, the description with reference to about x includes the description of x itself.
[0039] In addition, it should be understood that the reference to between two values or parameters in this document includes (and describes) aspects that include these two values or parameters properly. For example, the description with reference to between x and y includes the description of x and y
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13/23 properly.
[0040] The mass fractions disclosed in this document can be converted into a percentage by weight by multiplying by 100.
[0041] In the preferred embodiments of the present invention, the hygienic article is a diaper, a product for adult incontinence, a sanitary napkin or a feminine hygiene product. In certain preferred embodiments, hygienic articles can be formed according to one or more well-known configurations. Hygienic articles having well-known configurations may also include one or more adhesive fasteners and / or one or more elastic elements consisting of one or more of the biodegradable polymers disclosed in the present document with a higher bio-based content. In addition, one or more adhesive fasteners and / or one or more elastic elements can be formed according to one or more well-known configurations. In the preferred embodiments, the hygienic article has a biological and / or biodegradable base.
[0042] Preferred embodiments of the present invention can include one or more polymers having a β-lactone having a biobased content as a monomer, intermediate or reagent. Β-lactone monomers can be formed from the carbonylation of an epoxide with carbon monoxide, in the presence of a carbonylation catalyst. In certain preferred embodiments, the epoxide is ethylene oxide that can undergo a carbonylation reaction with carbon monoxide in the presence of a carbonylation catalyst to produce a β-lactone. In some modalities, epoxide is selected from the group that
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14/23 consists of: propylene oxide, 1,2-epoxybutane, 2,3epoxybutane, cyclohexene oxide; cyclopentane oxide, 1,2-epoxyhexane, 1,2-epoxidodecane, 2-cyclohexyloxirane, 3,3,3-Trifluor-1,2-epoxypropane, styrene oxide, glycidylbutyl ether, t-butyldimethylsilyl glycidyl ether, benzyl ether glycidyl. In certain embodiments, the epoxide is ethylene oxide.
[0043] In some embodiments, β-lactone may be βbutyrolactone, β-valerolactone, β-heptanolactone, βtridecanolactone, cis-3,4-dimethyloxetan-2-one, 4- (but-3-en1-yl) oxethane- 2-one, 4- (butoxymethyl) -2-oxetanone, 4 [[[(1,1-dimethylethyl) dimethylsilyl] oxy] methyl] -2-oxetanone, 4 [(2-propen-1-yloxy) methyl] - 2-oxetanone, 4- [(benzoyloxy) methyl] -2-oxetanone. In certain embodiments, βlactone is β-propiolactone.
[0044] Preferred embodiments of hygienic articles include a topsheet comprising a biodegradable polyester polyol polymer. The biodegradable polyester polymer can be foamed to form a network with pores. The foam can be impregnated with superabsorbent polymer. In some embodiments, the superabsorbent polymer can be dispersed heterogeneously within the foam, so that it is mechanically held in place. In some embodiments, the superabsorbent polymer can be impregnated so that it is heterogeneously contained in the foam pores.
[0045] In preferred embodiments, the monomers of polyester polyol polymers can be produced from renewable and / or recycled carbon sources. In certain preferred embodiments, β monomers
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15/23 lactone from polyester polyol polymers can be produced from carbonylation of an epoxide with carbon monoxide. Epoxide sources and carbon monoxide sources can have high bio-based carbon content. Β-lactone monomers can react with monomers with hydroxyl functional groups, such as simple alcohols, diols, triols and sugar alcohols with a high carbon content of bio-based. Advantageously, the polyester polyol polymers of the present invention can have an increased biodegradability and can have an increased content of biological base. In certain preferred embodiments, the polyols can be reacted with β-lactone monomers with a higher bio-based content to produce modified polyols with a higher bio-based content.
[0046] In certain preferred embodiments, polyester polyol polymers can include multiple functional groups carbonyl, carbonate, acetal, ether, nitrile, urethane, urea, imide, anhydride, phosphate and / or cyanocrilate in the main chain to facilitate biodegradability. The polyol includes cross-links between the polymer's main chains, allowing the formation of pores in a three-dimensional structure. The composition of the polyol and the crosslinking molecules can determine the pore size and the general structural properties of the polyol network. In some embodiments, crosslinking agents may include vinyl groups, for example, N, N'methylene-bisacrylamide, N, N'-ethylene-bis-methacrylamide, hexamethylene-bis-acrylamide, trialylamine, ethylene glycol dimethacrylate, trimethylolpropane trimethacrylate , pentaerythritol trimethacrylate and allyl methacrylate.
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16/23 [0047] The top sheet morphology can be created by any method that produces a physical mixture in which particles separated from the superabsorbent particles are interspersed as a physical mixture through a matrix of the biodegradable polyester polyol polymer. The physical mixture can be homogeneous. Alternatively, the physical mixture may be inhomogeneous, as described above, such that the concentration of the separated particles varies in different regions of the topsheet. The size of the separated particles can vary from 20 micrometers or less to as large as the desired thickness of the topsheet. Preferably, the volume and / or mass for the particles will be less than the respective volume or mass of the matrix. In the case of an upper sheet polymer that defines a network or pore size, the pore size and general structural properties of the polyol network can determine a capacity for the superabsorbent polymer and the interconnected dispersion distance for the superabsorbent polymer.
[0048] In the aspects that provide the top sheet in the form of a foam with pores, the foamy pores will generally have a spherical shape. The size or diameter of such spherical pores of polyester polyol polymer foams will not necessarily be the same size for all pores, but can be characterized as an average pore size, i.e., average pore diameter. In certain aspects of the invention, the pore volume can vary from face to face of the topsheet to provide regions with different pore sizes or pore density. In certain aspects of the invention, each
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17/23 porous region may have a different average pore size. Each region may also have a different distribution on this average, for example, a region may contain pores with an average diameter of 130 micrometers with 90% of all pores definable between about 80 micrometers and 180 micrometers, while the distinct region may contain pores with an average diameter of 50 micrometers with 90% of all pores definable between 20 micrometers and 80 micrometers.
[0049] In certain embodiments, the polyester polyol polymeric network can be formed by conventional foaming techniques for the production of foam structures such as blowing. In some embodiments, the interconnected open cell foam structure may include at least two distinct pore size regions. Larger pore size foams can acquire fluid quickly, but they cannot distribute the fluid sufficiently against the force of gravity or store the fluid effectively. On the other hand, foams with smaller pore sizes can absorb the fluid against the force of gravity and contain the fluid preventing it from coming into contact with the user's skin. Advantageously, these heterogeneous foams have several applications, such as fluid absorption and isolation.
The preferred foams of the present invention will have one or more pore regions suitable for absorbing liquids with an average pore diameter between about 20 and about 200 pm, preferably between about 50 and about 190 pm and more preferably between about 80 and about 180 pm. These foams will preferably also have one or more liquid-absorbing regions,
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18/23 having an average cell diameter of no more than about 50 pm, preferably about 5 to about 35 pm.
[0051] In certain preferred embodiments, the foam can be impregnated with superabsorbent polymer. In certain embodiments, the superabsorbent polymer can be impregnated in the pores of the polyester polyester polymer network. In some embodiments, the superabsorbent polymer may be more highly concentrated in an adjacent region and close to the absorbent core. Advantageously, the modalities of the present invention can more effectively transport liquids from one or more parts of the body of a biological organism and
store the liquids, keeping to same time the characteristics biodegradability and content from the base biological.[0052] The modalities favorite From articles hygienic
include an absorbent core made of superabsorbent polymer. The superabsorbent polymer can include a cross-linked and / or partially neutralized polyacrylic acid polymer, including cross-linked polyacrylic acids or cross-linked starch acrylic acid polymers. Superabsorbent polymers can absorb large amounts of liquids, including body fluids, such as urine or blood, and swell and retain aqueous liquids under a certain pressure, according to the general definition of a superabsorbent polymer. Suitable superabsorbent polymers are described in the USSN (Order serial number related to the superabsorbent polymer to be inserted) deposited________________ and their incorporation into said document being carried out
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19/23 as a reference.
[0053] In certain embodiments, superabsorbent polymers can be prepared by neutralizing unsaturated carboxylic acids or their derivatives, such as acrylic acid, alkali metal (eg, sodium and / or potassium) or ammonium salts of acrylic acid, alkyl acrylates and similar in the presence of a caustic treatment, such as sodium hydroxide, and then polymerizing the product with a relatively small amount of an internal, or monomeric cross-linking agent, such as a di- and / or polyfunctional monomer. The di- and / or polyfunctional monomeric materials can also serve as internal crosslinking agents to slightly crosslink the polymer chains. Cross-links can make the superabsorbent polymers insoluble in water, but water absorbent. These slightly crosslinked superabsorbent polymers contain a multiplicity of carboxyl groups attached to the polymer structure. The carboxyl groups can generate an osmotic driving force for the absorption of liquids by the cross-linked polymeric network.
[0054] In certain preferred embodiments, the superabsorbent polymer can be formed by combining βpropiolactone with a metallic compound to produce acrylic acid, a salt thereof or a combination thereof; and polymerizing the acrylic acid, a salt thereof, or a combination thereof with a polymerization initiator and preferably a crosslinking agent to produce the superabsorbent polymer. In some variations of the foregoing, polymerization is carried out pure or in non-aqueous media. In some variations, the metal compound is M,
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20/23
Μ, Μ2Ο, MOH, or M ⁺ (CH2 = CHCOCr) or a combination thereof.
[0055] In certain preferred embodiments, ο superabsorbent polymer can be formed by combining βpropiolactone with a metallic compound to produce acrylic acid, a salt thereof or a combination thereof; and polymerizing the acrylic acid, a salt thereof, or a combination thereof with a polymerization initiator and preferably a crosslinking agent to produce the superabsorbent polymer. In some variations of the foregoing, the polymerization is carried out pure or in a non-aqueous medium. In some variations, the metal compound is Μ, M2O, MOH, or M ⁺ (CH2 = CHCOO ~) or a combination thereof.
[0056] In certain embodiments, the superabsorbent polymer can produce our methods or processes comprising:
a) polymerization of β-propiolactone with an ionic initiator in a reactor to produce a polymeric intermediate, wherein the polymeric intermediate has a polyacrylic acid structure and a plurality of polypropiolactone side chains;
b) increasing the temperature of the reactor to produce acrylic acid from at least a portion of the side chains in the polymeric intermediate, and producing the acrylate polymer from at least a portion of the polymeric structure of the polymeric intermediate by thermolysis of the polymeric intermediate;
c) adding a metallic compound of the formula Μ, M2O, MOH, or M ⁺ (CH2 = CHCOO ~) or a combination of them, to the reactor to neutralize at least partially the acrylic acid in the reactor, in order to produce a mixture, on what
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21/23 the mixture in the reactor comprises acrylic acid and M ⁺ (CH2 = CHCOO -), where M is a Group I metal; and
d) polymerizing at least a portion of the mixture in the reactor to produce the polymer, wherein the polymer comprises repeated units of _{or or} ,. ~ (ΧΌ H. O ^ O'M * a combination of them.
[0057] In some variations of the preceding, steps (c) and (d) are performed without mixing or dilution or in a non-aqueous medium. In some embodiments, the polymer is cross-linked. Crosslinking agents can include vinyl groups, for example, N, N'-methylene-bisacrylamide, N, N'ethylene-bis-methacrylamide, hexamethylene-bis-acrylamide, trialylamine, ethylene glycol dimethacrylate, trimethylolpropane trimethacrylate trimethacrylate and ally methacrylate. Preferred embodiments of the disclosed processes provide a superabsorbent polymer that has a biological and / or biodegradable base.
[0058] In preferred embodiments, the backsheet of the present invention includes polylactone, derivatives of polybutylene succinate and / or polybutylene succinate. In certain preferred embodiments, the backsheet may consist of polylactone polymers comprising β-lactone monomers having linear chains of repeating monomeric units (O (CH2) 2-CO) _x containing carbon and oxygen atoms provided by a feed of β-lactone produced from the carbonylation of an epoxide containing carbon atoms that originate from a bio-based source. In some embodiments, polylactone polymers include crosslinking agents,
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22/23 such as vinyl groups, for example, N, N'-methylenebisacrylamide, N, N'-ethylene-bis-methacrylamide, hexamethylene-bis-acrylamide, trialyl amine, ethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, trimethacrylate and trimethacrylate and ally methacrylate. In certain preferred embodiments, polylactones may have or be modified to exhibit a higher degree of hydrophobicity.
[0059] The polylactone polymers of the present invention can have the following formula:
CO ....................
£ >> í p «'ps -' ·· ' ^x ' · '' anionic nucleophile cation carbonylation catalyst
OC “tion where Init- is an anionic nucleophile and Cat + is [0060] The appropriate anionic nucleophiles cation.
include R ^X O ^-
R ^X C (= O) O ^- , R ^X S ^- , R ^X O (C = O) O ^- , a halide (for example, Brq I ^- , Cl ^- ), R ^X (SÜ2) O ^- and PR ^X ₃ O ^- , in which each R ^x is independently selected from hydrogen, optionally substituted aliphatic, optionally substituted heteroaliphatic, optionally substituted aryl and optionally substituted heteroaryl.
[0061] In certain modalities, Inic- is RxC (= O) O-, Rx is selected from optionally substituted aliphatic, optionally substituted fluorinated aliphatic, optionally substituted heteroaliphatic, optionally substituted aryl, fluorinated aryl and optionally substituted heteroaryl. For example, in certain respects, the Init- may be CH2 = CHCO2-, CH3CO2- or CF3CO2-.
[0062] In certain modalities, Init- is RxO-, Rx is selected from optionally substituted aliphatic,
Petition 870190052275, of 6/4/2019, p. 34/41
Optionally substituted heteroaliphatic, optionally substituted aryl, and optionally substituted heteroaryl. For example, in certain respects, Init- is hydroxide, methoxide or ethoxide.
[0063] In certain modalities, Cat + is selected from the group consisting of Li +, Na +, K +, Mg2 +, Ca2 + and A13 +. In some modalities, Cat + is Na +. In some ways, Cat + is an organic cation. In some variations, the organic cation is selected from the group consisting of quaternary ammonium, imidazolium and bis (triphenylphosphine) imine. In some variations, the quaternary ammonium cation is tetra alkyl ammonium.
[0064] The modalities described in this document are not intended to be limited to the aspects shown, however they must be in accordance with the broader scope consistent with the principles and characteristics revealed in this document.

权利要求:
Claims (23)
[1]
1. Biodegradable hygienic article, characterized by the fact that it comprises:
a) a topsheet comprising a biodegradable polyester polymer with a heterogeneous dispersion of a superabsorbent polymer retained therein;
b) an absorbent core comprising a biodegradable superabsorbent polymer having an inner side positioned adjacent and fixed with respect to said topsheet; and,
c) a backsheet comprising a biodegradable polylactone polymer positioned adjacent an external side of said absorbent core and fixed in relation to said adsorbent core.
[2]
2. Hygienic article according to claim 1, characterized by the fact that the superabsorbent polymer is dispersed in the top sheet as separate particles.
[3]
3. Biodegradable hygienic article, according to claim 1, characterized by the fact that said upper sheet has an absorbent face positioned adjacent to said adsorbent core and a corporeal face on an external face of the hygienic article and the concentration of nearby superabsorbent polymer to the body face being higher in relation to the concentration of superabsorbent polymer close to the absorbent face.
[4]
4. Hygienic article, according to claim 3, characterized by the fact that the separated particles have an average diameter greater than 20 pm and less than the average thickness of the upper sheet.
[5]
5. Hygienic article according to claim 1,
Petition 870190052275, of 6/4/2019, p. 36/41
2/5 characterized by the fact that the polymer comprises a foam.
[6]
6. Hygienic article according to any one of claims 1 to 3, characterized in that the polyol polyester polymer has pores impregnated with the superabsorbent polymer.
[7]
7. Hygienic article according to claim 6, characterized by the fact that 90% of the pores have an average diameter of at least 20 pm and not more than 180 pm.
[8]
8. Biodegradable hygienic article according to claim 6, characterized by the fact that said top sheet comprises at least a first porous region adjacent and close to said body face and a second porous region adjacent and close to said central face pad.
[9]
9. Biodegradable hygienic article according to claim 8, characterized by the fact that said first porous region has smaller pore sizes than said second region.
[10]
10. Biodegradable hygienic article according to claim 9, characterized by the fact that said second porous region includes pores that have a higher concentration of superabsorbent polymer than said first porous region.
[11]
11. Biodegradable hygienic article according to claim 1, characterized in that said backsheet comprises biodegradable polylactone polymers that have a hydrophobic characteristic.
[12]
12. Biodegradable hygienic article, according to
Petition 870190052275, of 6/4/2019, p. 37/41
3/5 claim 1, characterized by the fact that the biodegradable hygienic article includes one or more elastic elements formed from one or more biodegradable polyester polyol polymers, derivatives of biodegradable polyacrylic acid and a biodegradable polylactone polymer.
[13]
13. Biodegradable hygienic article according to claim 1, characterized in that the biodegradable hygienic article includes one or more adhesive fasteners formed from one or more biodegradable polyester polyol polymers, derivatives of biodegradable polyacrylic acid and polylactone polymer biodegradable.
[14]
14. Hygienic article according to claim 1, characterized by the fact that the biodegradable polyol polyester polymer of the top sheet includes one or more functional groups selected from the group consisting of carbonyl, carbonate, acetal, ether, nitrile, urethane, urea, imide, anhydride, phosphate, cyanocrylate functional groups and combination thereof.
[15]
15. Hygienic article according to claim 6, characterized by the fact that the polyol polymer of the top sheet includes cross-links between the main polymeric chains that allow the formation of pores in a three-dimensional structure.
[16]
16. Hygienic article according to any one of claims 1 to 3, characterized in that the biodegradable polylactone polymer of the backsheet comprises polylactone, polybutylene succinate, and polybutylene succinate derivatives in addition to their combinations.
Petition 870190052275, of 6/4/2019, p. 38/41
4/5
[17]
17. Hygienic article according to any one of claims 1 to 3, characterized in that the absorbent core is formed from a polymer containing β-propiolactone monomers.
[18]
18. Biodegradable hygienic article, characterized by the fact that it comprises:
a) a topsheet comprising a polymeric network of biodegradable polyester polyol having pores impregnated with a heterogeneous dispersion of a biodegradable superabsorbent polymer;
b) an absorbent core comprising a biodegradable superabsorbent polymer having an inner side positioned adjacent and fixed with respect to said topsheet; and,
c) a backsheet comprising a biodegradable polylactone polymer positioned adjacent an external side of said absorbent core and fixed with respect to said adsorbent.
[19]
19. Biodegradable hygienic article according to claim 18, characterized by the fact that said upper sheet comprises an absorbent central face positioned adjacent to said adsorbent core and a corporeal face.
[20]
20. Biodegradable hygienic article, according to claim 19, characterized by the fact that said upper sheet comprises at least a first porous region adjacent and close to said body face, and a second porous region adjacent and in the vicinity of said face of absorbent core.
[21]
21. Biodegradable hygienic article, according to
Petition 870190052275, of 6/4/2019, p. 39/41
5/5 claim 20, characterized by the fact that said first porous region has smaller pore dimensions than said second region.
[22]
22. Biodegradable hygienic article according to claim 21, characterized by the fact that said second porous region includes pores presenting a higher concentration of superabsorbent polymer than said first porous region.
[23]
23. Biodegradable hygienic article according to claim 18, characterized in that said backsheet comprises biodegradable polylactone polymers that have or are modified to have a hydrophobic characteristic.

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同族专利:

公开号 | 公开日

US20180153746A1|2018-06-07|

KR20190085162A|2019-07-17|

AU2017372873A1|2019-06-20|

JP2020500616A|2020-01-16|

US10500104B2|2019-12-10|

CN110035723A|2019-07-19|

EP3551149A4|2020-06-17|

MX2019006587A|2019-08-14|

EP3551149A1|2019-10-16|

MA49813A|2020-06-17|

WO2018106824A1|2018-06-14|

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